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Ryan Gosling and Rachel McAdams (Noah & Allie - The Notebook) - Hot damn, did they have sexual chemistry.
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Ahhhh, yessss! Their chemistry was amazing.
I find that often RL couples can't translate their chemistry to on-screen (i.e. Penn/Blake as Dan/Serena), but Ryan & Rachel were just as adorable and connected on-screen as they were as a couple off-screen.