Oh I wanted to remember their first kiss.
When reading the old post, I do recall that when they first met i thought that Riley think Buffy was shallow or something like that, he was more interested in other topics, talking with Willow about Psicology and all that. But never believe he had any interest in Willow.
My guess was he thought that Buffy was a silly blond girl, and he wasn't into them that's for sure.